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AMF - Implementing Agreement on Advanced Motor Fuels

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Diesel engines for additized ethanol

In Sweden ethanol is used in the diesel combustion process in Scania’s ethanol engine by using ignition improver and lubricity additive. The first ethanol bus equipped with Scania’s engine started service in 1985, and in 2000 there were 407 buses running in Sweden. Now more than 600 buses have been supplied by Scania. Today ethanol buses are running also in other countries, for example, in Mexico, Australia, and Denmark.

The modifications of diesel engines for ethanol-use include e.g. increased compression ratio, a special fuel injection system and a special catalyst to control aldehyde emissions. Scania's current 3

generation ethanol engine is an adaptation of Scania's latest 9-litre diesel engine with air-to-air charge cooling and exhaust gas recirculation, EGR. The ethanol version features, among other things, elevated compression ratio (28:1) to facilitate ignition, higher fuel delivery to compensate lower energy density of the fuel, and special materials for the fuel system. The engine is available with Euro V and EEV emission certification (Scania 2007, Nylund 2011).

 

IEA AMF work on diesel engines for additized ethanol:

  • Annex 46, 2013–2015 “Alcohol Application in CI Engines”. Neat alcohols can be applied at very high compression ratios in diesel engines with the same performance as conventional diesel fuel by applying ignition improvers ." download report (key messages).
  • Annex 35-1, -2008 : “Ethanol as fuel for road transport”, download report
  • Annex 26, 2002-2005: “Alcohols and Ethers as Oxygenates in Diesel Fuels”, download report

 

Fuel properties

The fuel used in ethanol buses in Sweden is called Etamax D. It contains 92 % m/m of hydrated ethanol (grade 95%), 5.0 % m/m ignition improver (poly-ethylene-glycol derivative from Akzo Nobel, Beraid 3540), 2.8 % m/m denaturants (2.3 % m/m MTBE and 0.5% m/m isobutanol) and corrosion inhibitor additive. Etamax DTM fuel contains 6.4 % m/m water. (SEKAB brochure, Westman 2008). Later on, composition of Beraid additive may have changed. Today, also new commercial ignition improvers for Scania’s ethanol engine are available (Nylund et al. 2015).

In Sweden, standard SS 15 54 37 is specification for alcohols for high-speed diesel engines (Table 1). The standard does not include denaturants, ignition improvers or colorants.

Table 1. Selected properties of SEKAB's specification for Etamax DTM and Swedish SS 15 54 37 standard for ethanol used in high-speed diesel engines. Complete requirements are available from respective organizations.

 

Emission results

In IEA-AMF Annex 46 (Nylund et al. 2016), new commercial ignition improvers for alcohol application in diesel engine (Scania concept) are now available, and two of these were studied together with a well-known ignition improver. The project showed that neat alcohols can be applied at very high compression ratios in diesel engines with the same performance as conventional diesel fuel. The performance was achieved by applying different ignition improvers in the form of new as well as a well known additive. Blends of alcohols and diesel showed a reduction in particulate emissions from a compression ignition engine with lower compression ratios.These new ignition improvers worked well with ethanol in a Scania compression ignition engine with a very high compression ratio (28:1). For methanol, the fuel system of the engine needs to be modified in order to manage the higher amounts of fuel flow needed due to the lower calorific value of the fuel. The relative specific fuel consumption measurements are shown in Figure 1. The injection timing needs to be optimized for the individual fuels (alcohol + ignition improver), since the rate of heat release was found to differ from one fuel to the other. Also the effect of the changes in fuel water content on the engine performance was studied. Decreased fuel water content increased both CO and NOx emissions, whereas adding water reduced both these emissions marginally in comparison with the commercial hydrous fuel. Applying the selective catalytic reduction (SCR) for NOx control would diminish the role water for NOx. In addition, different blends of diesel and alcohols, methanol, ethanol and butanol, were tested in another Scania heavy-duty diesel engine with a lower compression ratio (16:1). The addition of alcohols to diesel was found to decrease particulate emissions in general, and the gaseous emissions were unchanged, except at idle operation at which aldehyde, carbon monoxide, and hydrocarbon emissions increased.

Figure 1. Specific fuel consumptions (IEA-AMF Annex 46 Nylund et al. 2016).

 

 

One part of the IEA-AMF Annex 46 reported by Nylund et al. (2016) explored possibilities to reduce the additive dosing by injecting part of the fuel into the intake manifold. Using intake manifold injection, 25 % of the standard additive dosing was sufficient to achieve normal combustion (ignition delay and rate of heat release), however, at the cost of increased fuel consumption. Further testing to optimise, e.g. amount of pilot fuel and timing of main fuel injection, is needed to really show the potential of the concept. One way to take advantage of this concept would be to keep the dosing of additive as it is, but to reduce the compression ratio, thus lowering both mechanical stresses and costs for the engine. The Scania ethanol engine used for the testing was equipped with unit injectors. A common-rail fuel system would enable pre-injection without any additional hardware. A significant reduction of additive dosing might jeopardise cold starting.

Earlier generations of Scania's ethanol buses showed exhaust emissions similar to advanced diesel buses equipped with an oxidation catalyst or particle filters, but higher emissions than those of sophisticated CNG buses (particularly the NOx emission). The smoke emission from ethanol buses was almost negligible (likewise buses on gaseous fuels).  Acetaldehyde emissions were high for ethanol buses, but the cancer risk index was low (similar EPA factors used as for E85). (Ahlvik 2001).

Nylund et al. (2011) studied two trucks and one bus equipped with Scania's new generation ethanol engines; all with the 8.9-litre 270 hp ethanol engine. As reference, three diesel trucks (Euro V), three diesel buses and two CNG buses (stoichiometric and lean-burn) were studied. In general, the NOx emissions from ethanol vehicles were average, but PM emissions lower (buses) or significantly lower (trucks) compared to diesel vehicles without particulate filters (even 75% reduction in PM). The stoichiometric CNG bus showed lowest, whereas the lean-burn CNG bus the highest NOx values. PM emissions were higher for ethanol than for CNG average (Figure 2). Energy consumption of the ethanol bus was some 8% higher, and for ethanol trucks marginally lower, than the average diesel. It was noticeable that for the CNG buses energy increase was close to 40%, respectively. The conclusions seems to be quite similar with the new and older generation of ethanol vehicles: exhaust emissions from ethanol vehicles are close to clean diesel vehicles equipped with NOx and PM reducing technologies, whereas the sophisticated stoichiometric CNG vehicles are the cleanest. 


Figure 2. NOx vs. PM emissions for buses. The results with ethanol bus is marked with red star. (Nylund et al. 2011).

 

References 

Ahlvik, P. (2001) Swedish Experiences from Low-Emission City Buses: Impact on Health and Environment. DEER´01, August 5-9, 2001. 

Larsen, U., Johansen, T. and Schramm, J. (2009) Ethanol as a fuel for road transportation. IEA-AMF Annex 35. http://virtual.vtt.fi/virtual/amf/pdf/annex35report_final.pdf

McCormick, R.L. and Parish, R. (2001) Technical Barriers to the Use of Ethanol in Diesel Fuel. National Renewable Energy Laboratory. Colorado 2001 (report NREL/MP-540-32674). 

Nylund, N.-O., Laurikko, J., Laine, P., Suominen, J., Anttonen, M. P. (2011) Benchmarking HD Ethanol Vehicles Against Diesel and CNG Vehicles. XIX International Symposium on Alcohol Fuels ISAF, Verona, Italy. October 10th - 14th, 2011.

Nylund, Nils-olof, Timo Murtonen, Mårten Westerholm, Christer Söderström, Timo Huhtisaari, and Gurpreet Singh. 2015. “Testing of Various Fuel and Additive Options in a Compression-Ignited Heavy-Duty Alcohol Engine.” In The 21st International Symposium on Alcohol Fuels, 10 March 2015 , Gwangju, Korea., 1–15. (Note IEA-AMF Annex 46 report: http://www.iea-amf.org/app/webroot/files/file/Annex%20Reports/AMF_Annex_46.pdf).

Scania (2007) Scania continues renewable fuel drive. New highly efficient diesel-ethanol engine - ready to cut fossil CO2 emissions by 90%. Press info 21.5.2007.

Westman, B. (2008) Ethanol fuel in diesel engines for energy efficiency. BAFF – Bioalcohol fuel foundation. Conference on sustainable ethanol. Gothenburg, Sweden. 26 May 2008.